Department
Chemistry
Journal Title
Acta Crystallographica Section E
Publication Date
2012
Volume No.
E68
First Page
m1158
Last Page
m1159
Publisher
Wiley
File Name
082_Whited-Matthew_TransAcetyldicarbonyl.pdf
Abstract
The title compound, [Mo(C5H5)(C2H3O)(C13H13P)(CO)2], was prepared by reaction of [Mo(CH3)(C5H5)(CO)3] with methyldiphenylphosphane. The MoII atom exhibits a fourlegged piano-stool coordination geometry with the acetyl and phosphane ligands trans to each other. There are several intermolecular C—HO hydrogen-bonding interactions involving carbonyl and acetyl O atoms as acceptors. A close nearly parallel – interaction between the cyclopentadienyl plane and the phenyl ring of the phosphane ligand is present, with an angle of 6.4 (1) between the two least-squares planes. The centroid-to-centroid distance between these groups is 3.772 (3) A˚ , and the closest distance between two atoms of these groups is 3.449 (4) A˚ . Since each Mo complex is engaged in two of these interactions, the complexes form an infinite - stack coincident with the a axis.
Rights Management
Carleton College does not own the copyright to this work and the work is available through the Carleton College Library following the original publisher's policies regarding self-archiving. For more information on the copyright status of this work, refer to the current copyright holder.
RoMEO Color
Green
Preprint Archiving
Yes
Postprint Archiving
No
Publisher PDF Archiving
Yes
Fully Open Access
Yes
Contributing Organization
Carleton College
Type
Article
Format
application/pdf
Language
English
DOI
10.1107/S1600536812034307
Recommended Citation
Whited, Matthew T., Joseph W. Boerma, Michael J. McClellan, Christian E. Padilla, and Daron E. Janzen., "trans-Acetyldicarbonyl(g5 -cyclopentadienyl)(methyldiphenylphosphane)- molybdenum(II)". Acta Crystallographica Section E. 2012, E68: m1158-m1159. Available at: https://doi.org/10.1107/S1600536812034307. Accessed via Faculty Work. Chemistry. Carleton Digital Commons. https://digitalcommons.carleton.edu/chem_faculty/8
The definitive version is available at https://doi.org/10.1107/S1600536812034307
